Crystal structure of fac-[2-(4-methyl-5-phenylpyridin-2-yl)phenyl-κ2 C 1,N]bis[2-(pyridin-2-yl)phenyl-κ2 C 1,N]iridium(III)
نویسندگان
چکیده
In the title compound, [Ir(C11H8N)2(C18H14N)], the IrIII ion adopts a distorted octa-hedral coordination environment defined by three C,N-chelating ligands, one stemming from a 2-(4-phenyl-5-methyl-pyridin-2-yl)phenyl ligand and two from 2-(pyridin-2-yl)phenyl ligands, arranged in a facial manner. The IrIII ion lies almost in the equatorial plane [deviation = 0.0069 (15) Å]. In the crystal, inter-molecular π-π stacking inter-actions, as well as inter-molecular C-H⋯π inter-actions, are present, leading to a three-dimensional network.
منابع مشابه
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عنوان ژورنال:
دوره 72 شماره
صفحات -
تاریخ انتشار 2016